Highly Conductive and Stretchable Hydrogel Nanocomposite Using Whiskered Gold Nanosheets for Soft Bioelectronics

Abstract The low electrical conductivity of conductive hydrogels limits their applications as soft conductors in bioelectronics. This low conductivity originates from the high water content of hydrogels, which impedes facile carrier transport between conductive fillers. This study presents a highly conductive and stretchable hydrogel nanocomposite comprising whiskered gold nanosheets. A dry network of whiskered gold nanosheets is fabricated and then incorporated into the wet hydrogel matrices. The whiskered gold nanosheets preserve their tight interconnection in hydrogels despite the high water content, providing a high‐quality percolation network even under stretched states. Regardless of the type of hydrogel matrix, the gold‐hydrogel nanocomposites exhibit a conductivity of ≈520 S cm −1 and a stretchability of ≈300% without requiring a dehydration process. The conductivity reaches a ma…