Cation Exchange in Colloidal Transition Metal Nitride Nanocrystals

Transition metal nitride (TMN)-based nanostructures have emerged as promising materials for diverse applications in electronics, photonics, energy storage, and catalysis due to their highly desirable physicochemical properties. However, synthesizing TMN-based nanostructures with designed compositions and morphologies poses challenges, especially in the solution phase. The cation exchange reaction (CER) stands out as a versatile postsynthetic strategy for preparing nanostructures that are otherwise inaccessible through direct synthesis. Nevertheless, exploration of the CER in TMNs lags behind that in metal chalcogenides and metal phosphides. Here, we demonstrate cation exchange in colloidal metal nitride nanocrystals, employing Cu 3 N nanocrystals as starting materials to synthesize Ni 4 N and CoN nanocrystals. By controlling the reaction conditions, Cu 3 N@Ni 4 N and Cu 3 N@CoN core@shel…