“Majority‐Rules” Effect on Supramolecular Chirality and Optoelectronic Properties of Chiral Tetrachloro‐Perylene Diimides

Abstract Supramolecular chirality has attracted a great deal of attention as a platform for both fundamental study and chirality amplification in various research fields. Compared with the “sergeants‐and‐soldiers” principle, the “majority‐rules” principle, which affects chirality amplification in supramolecular systems, is rarely reported for nano/microstructures. Here, chiral tetrachloro‐substituted perylene diimides are synthesized that self‐assemble into chiral supramolecules with different degrees of enantiomeric excess (ee). Interestingly, it is found that quasi‐2D crystals are gradually transferred to 1D nanowires (NWs) with ee from 100% to 0%. In the racemic system, chiral self‐discrimination is observed due to the greater thermodynamic stability of heterochiral crystals than the homochiral counterparts, judging from the theoretical studies. Circular dichroism analysis indicates t…