Electrochemical Synthesis of NH3 at Low Temperature and Atmospheric Pressure Using a γ-Fe2O3 Catalyst

The electrochemical synthesis of NH 3 by the nitrogen reduction reaction (NRR) at low temperature (<65 °C) and atmospheric pressure using nanosized γ-Fe 2 O 3 electrocatalysts were demonstrated. The activity and selectivity of the catalyst was investigated both in a 0.1 M KOH electrolyte and when incorporated into an anion-exchange membrane electrode assembly (MEA). In a half-reaction experiment conducted in a KOH electrolyte, the γ-Fe 2 O 3 electrode presented a faradaic efficiency of 1.9% and a weight-normalized activity of 12.5 nmol h –1 mg –1 at 0.0 V RHE . However, the selectivity toward N 2 reduction decreased at more negative potentials owing to the competing proton reduction reaction. When the γ-Fe 2 O 3 nanoparticles were coated onto porous carbon paper to form an electrode for a MEA, their weight-normalized activity for N 2 reduction was found to increase dramatically to 55.9 n…