Fundamental Modeling and Experimental Investigation of Polymer Washing Process**This research is supported by ‘Basic research and optimization of polymer washing process after condensation reaction’, funded by the LG CHEM.
2016 · IFAC-PapersOnLine
저자
Sang Hwan Son, Dong Hwi Jeong, Hyun Woog Ryu, Joong Jin Han, 이종민 (Jong Min Lee)
연구주제
Fuel Cells and Related Materials · Polymer crystallization and properties
NTIS 과학기술표준분류
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AI 연구 키워드·방법
impurity diffusion polycondensation polymer washing process
키워드 (OpenAlex)
impurity removal impurity diffusion coefficient polycondensation polymer purity dimensionless parameters
초록
After polymerization reaction, impurities such as adduct, solvent and catalyst are trapped inside the polymers. These impurities should be removed by a polymer washing process to improve the purity of the polymer products. Also, the optimization of the polymer washing process is essential to reduce the energy, resources and processing time. This work provides theoretical basis for optimization of polymer washing process by proposing a fundamental model and experimental investigation method of the process. The model describes the impurity distribution inside the polymers, mole balance of impurities inside and outside of the polymers, and impurity diffusion rate at polymer surface. The experimental investigation with SPAEK (sulfonated poly(aryl ether ketone)) samples reports the impurity diffusion coefficient at polymer surface of the performed experiments. The computed D(the impurity diff…
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