Aspect-Ratio Effect of Nanorod Compatibilizers in Conducting Polymer Blends

Nanoparticles (NPs) at the interface between two different polymer blends or fluid mixtures can function as compatibilizers, thereby dramatically improving the interfacial properties of the blends or the fluid mixtures. Their compatibilizing ability is strongly dependent on their size, shape, and aspect ratios (ARs), which determines their adsorption energy to the interface as well as their entropic penalty when they are being strongly segregated at the interface. Herein, we investigated the effect of the ARs of nanorod surfactants on the conducting polymer blend of poly(triphenylamine) (PTPA) templated by polystyrene (PS) colloids. The lengths of the polymer-coated CuPt nanorods (CuPt NRs) were 5, 15, and 32 nm with a fixed width of 5 nm, thus producing three different AR values of 1, 3, and 6, respectively. For quantitative analysis, the morphological and electrical behaviors of the po…